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Electron Configuration and the Pascal
Triangle
The common character of theories of atomic
constitution has been the endeavour to find configurations and
motions of the electrons which would seem to offer an interpretation
of the variations of the chemical properties of the elements with
the atomic number as they are so clearly exhibited in the well-known
periodic law. A consideration of this law leads directly to the view
that the electrons atom are arranged in distinctly separate groups,
each containing a number of electrons equal to one of the periods in
the sequence of the elements, arranged according to increasing
atomic number. In the first attempts to obtain a definite picture of
the configuration and motion of the electrons in these groups it was
assumed that the electrons within each group at any moment were
placed at equal angular intervals on a circular orbit with the
nucleus at the centre, while in later theories this simple
assumption has been replaced by the assumptions that the
configurations of electrons with in the various groups do not
possess such a simple axial symmetry, but exhibit a higher degree of
symmetry in space, it being assumed, for instance, that the
configuration of the electrons at any moment during their motions
possesses polyhedral symmetry. The elecrtron can be analyzed in
several ways. Presently, the Bohr model of the atom will be used
which uses the shell model for evaluating electrons. The shell model
has electrons residing in various energy levels about the nucleus.
The first shell (K Shell) can have up to 2 electrons. This shell is
filled first with electrons, thus any atom with greater than 2
protons or atomic number will have this shell filled. The next shell
is the (L Shell) and can have up to 8 electrons in it. So on with
the (M Shell). When the number of electrons starts filling the (N
Shell) they then start packing in the inner shells. Electron shells
have limited capacity for electrons. The farther an electron shell
is from nucleus, the larger it is.
An easy way to calculate the total number of electrons that can
be held by a given energy level is to use the formula
2*n2 , where n equals the number of the
electron shell. For example, for the 1st electron shell n=1 and
2*12 = 2, telling us that the capacity of the 1st shell
is 2 electrons as we have already seen. For the 2nd shell ( n=2 )
and 2*22 = 8. For an atom to fill its 2nd electron shell,
10 electrons would be needed : 2 to fill the 1st shell and 8 to fill
the 2nd.
Principle energy level ( n ) |
Maximum number of electrons
2*n2 |
1 |
2 |
2 |
8 |
3 |
18 |
4 |
32 |
5 |
50 |
6 |
72 |
7 |
98 |
The maximum number of electrons is double square number.The
square numbers can be found in the next triangle's form of the
natural numbers :
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1 |
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1 |
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1 |
2 |
1 |
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4 |
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1 |
2 |
3 |
2 |
1 |
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9 |
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1 |
2 |
3 |
4 |
3 |
2 |
1 |
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16 |
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1 |
2 |
3 |
4 |
5 |
4 |
3 |
2 |
1 |
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25 |
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1 |
2 |
3 |
4 |
5 |
6 |
5 |
4 |
3 |
2 |
1 |
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36 |
| 1 |
2 |
3 |
4 |
5 |
6 |
7 |
6 |
5 |
4 |
3 |
2 |
1 |
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49 |
We may show a connection between square numbers and the
tetrahedral numbers :
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1 |
. |
. |
. |
. |
. |
1 |
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4 |
. |
. |
. |
. |
. |
4 |
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9 |
1 |
. |
. |
. |
. |
10 |
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16 |
4 |
. |
. |
. |
. |
20 |
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25 |
9 |
1 |
. |
. |
. |
35 |
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36 |
16 |
4 |
. |
. |
. |
56 |
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49 |
25 |
9 |
1 |
. |
. |
84 |
As you might expect, the 3rd shell has a total capacity of
2*32 = 18 electrons. But things get a bit tricky here.
Electron shells actually have sublevels. The first sublevel ( the
s sublevel ) holds 2 electrons. The second, p ,
sublevel holds 6.The third, d , sublevel holds 10. When
levels 3s and 3p are filled, electron shell#3 acts as if it has
reached capacity with only 8 total electrons. In other words, in an
atom with 20 electrons ( which is the element calcium) the first 2
electrons are located in the 1st shell, the next 8 in shell#2, the
following 8 in shell#3 and remaining 2 electrons are located in
shell#4.
The number of sublevels that an energy level can contain is equal
to the principle quantum number of that level. The first sublevel is
called s sublevel. s sublevels have one orbital, which
can hold up to two electrons. The second sublevel is called a
p sublevel. p sublevels have three orbitals, each of
which can hold 2 electrons, for a total of 6. The third sublevel is
called a d sublevel and d sublevels have 5 orbitals,
for a possible total of 10 electrons. The fourth sublevel is called
an f sublevel. f sublevels, with 7 orbitals, can hold
up to 14 electrons. Although energy levels that are higher than 4
would contain additional sublevels, these sublevels have not been
named because no known atom in its ground state would have electrons
that occupy them. The information about the sublevels is summarized
in the table below :
|
Orbital and
Electron Capacity for the
Sublevels |
| Sublevel |
# of
orbitals |
Maximum number of
electrons |
| s |
1 |
2 |
| p |
3 |
6 |
| d |
5 |
10 |
| f |
7 |
14 |
| ... |
9 |
18 |
| ... |
11 |
22 |
| ... |
13 |
26 |
| ... |
15 |
30 |
The maximum numbers of electrons in sublevels may be represented
as the following triangle's form of numbers :
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2 |
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2 |
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2 |
2 |
2 |
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6 |
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1 |
3 |
2 |
3 |
1 |
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10 |
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1 |
1 |
4 |
2 |
4 |
1 |
1 |
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14 |
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1 |
1 |
1 |
5 |
2 |
5 |
1 |
1 |
1 |
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18 |
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1 |
1 |
1 |
1 |
6 |
2 |
6 |
1 |
1 |
1 |
1 |
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22 |
The law of the electron configurations is the law of the
geometrical area. There is a connection between odd numbers and the
square numbers :
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1 |
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1 |
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3 |
1 |
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4 |
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5 |
3 |
1 |
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9 |
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7 |
5 |
3 |
1 |
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16 |
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9 |
7 |
5 |
3 |
1 |
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25 |
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11 |
9 |
7 |
5 |
3 |
1 |
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36 |
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13 |
11 |
9 |
7 |
5 |
3 |
1 |
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49 |
There is also a connection between odd numbers and the triangular
numbers :
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1 |
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1 |
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3 |
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3 |
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5 |
1 |
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6 |
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7 |
3 |
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10 |
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9 |
5 |
1 |
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15 |
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11 |
7 |
3 |
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21 |
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13 |
9 |
5 |
1 |
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28 |
The odd numbers , square numbers and pyramidal numbers can be found as columns
in Pascal triangle of the second kind :
1 1
2 1 3
2 1 4 5 2 1 5 9 7 2 1 6 14 16 9 2 1 7 20 30
25 11
2 1 8 27 50 55 36 13 2 1 9 35 77
105 91 49
15 2
An electron configuration is
a method of indicating the arrangement of electrons about a nucleus.
A typical electron configuration consists of numbers, letters and
superscripts with the following format: 1. A number indicates
the energy level.( The number is called the principal quantum
number.) 2.A letter indicates the type of orbital:
s,p,d,f... 3.A superscript indicates the number of electrons in
the orbital. To write an electron configuration: 1.Determine
the total number of electrons to be represented. 2.Use the Aufbau
process to fill the orbitals with electrons. The Aufbau process
requires that electrons fill the lowest energy orbitals first. In
another words, atoms are built from the ground upwards. 3.The sum
of the superscripts should equal the total number of electrons.
The periodic table lines up elements in order of the # of protons (atomic number), but the key to the columns is the number of valence (outermost) electrons. To simplify things chemists picture electrons filling shells such that once a shell is filled we only become concerned with electrons outside the full shell. Consider the first two elements hydrogen and helium. With two electrons and the inertness of helium, it has a shell that is full and is stable. Hydrogen can have valences of no electrons, one electron, or two electrons. With the case of hydrogen with two electrons it is pictures as having a full shell (called the "NOBLE GAS ELECTRON CONFIGURATION").
After a pair of electrons, the next shell requires eight electrons (called an 'OCTET'). This element is neon, with atomic number 10, with two electrons in the first shell and the next shell of eight being full. With the shells full, this is what allows neon
to be unreactive (and known as a "NOBLE GAS"). Thus a great example of valence electrons
dictating an elements postion on the periodic table is the fluorine atom above the chlorine
atom. Both of these elements have seven valence electrons outside their respective noble
gas electron configurations. Fluorine is the most reactive atom needing one more electron
to complete the octet outside the inner electron pair. This is where even with the nine
protons (providing an electric charge of positive +9), the fluorine atom requires 10
electrons to be stable (so in water the fluorine anion, F- is how you would find
it-resembling the noble gas electron configuration of neon)...Chlorine has 17 protons
(and positive +17 electric charge) but would be stable with 18 electrons since
two would fill the first helium shell, then eight to fill the neon shell, and with only
seven for the next noble gas shell (resembling argon), an extra electron makes the
chloride anion stable in water, Cl-, 18 electrons (2,8,8=2+8+8=18e-'s)...
In the atomic shell model, the shells are filled
with electrons in order of increasing energy until they completely
fill a closed shell, producing the inert core of a noble gas. These
elements have highly stable properties:
|
# |
Case |
Electron
Configuration |
Geometrical Number of electrons
|
Real Number of electrons |
|
1 |
Geometrical |
2 |
2
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He |
2 |
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2 |
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2 |
Geometrical |
2,2-6 |
10
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Ne |
2,2-6 |
|
10 |
|
3 |
Geometrical |
2,2-6,2-6-10 |
28
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Ar |
2,2-6,2-6-* |
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18 |
|
4 |
Geometrical |
2,2-6,2-6-10,2-6-10-14 |
60
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Kr |
2,2-6,2-6-10,2-6-*-* |
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36 |
|
5 |
Geometrical |
2,2-6,2-6-10,2-6-10-14,2-6-10-14-18 |
110
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Xe |
2,2-6,2-6-10,2-6-10-*,2-6-*-*-* |
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54 |
|
6 |
Geometrical |
2,2-6,2-6-10,2-6-10-14,2-6-10-14-18,2-6-10-14-18-22 |
182
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Rn |
2,2-6,2-6-10,2-6-10-14,2-6-10-*-*,2-6-*-*-*-* |
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86 |
Geometrical Number of electrons is equivalent with
the duble pyramidal numbers :
2,10,28,60,110,182,...=
2*(1,5,14,30,55,91,...)
Real Number of electrons is :
2,10,18,36,54,86,...=
2*(1,5,9,18,27,43,...)
We have series : 2,18,54,118,218...
Magic numbers are featured by the formula:
ZE1m=4*(2*m3+3*m2+m-3)/6
m = 1,2,3 4, 5, 6, 7 ...
And the series : 10,36,86,168...
Magic numbers are featured by the formula:
ZE2m=4*(2*m3+6*m2+7*m)/6
m = 1,2,3 4, 5, 6, 7 ...
The connection between magic numbers of noble gases on one side
and pyramidal numbers, on the other, is highly amusing :
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1 |
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= |
1 |
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2 |
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5 |
+ |
1 |
- |
1 |
= |
5 |
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10 |
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5 |
+ |
5 |
- |
1 |
= |
9 |
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18 |
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14 |
+ |
5 |
- |
1 |
= |
18 |
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36 |
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14 |
+ |
14 |
- |
1 |
= |
27 |
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54 |
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30 |
+ |
14 |
- |
1 |
= |
43 |
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86 |
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30 |
+ |
30 |
- |
1 |
= |
59 |
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118 |
There is a connection between magic numbers of noble gases on one side and pyramidal and square numbers, on the other
:
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1 |
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= |
1 |
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2 |
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5 |
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= |
5 |
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10 |
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5 |
4 |
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= |
9 |
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18 |
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14 |
4 |
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= |
18 |
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36 |
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14 |
9 |
4 |
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= |
27 |
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54 |
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30 |
9 |
4 |
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= |
43 |
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86 |
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30 |
16 |
9 |
4 |
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= |
59 |
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118 |
Here is a connection between real number of
electrons and square numbers:
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1 |
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= |
1 |
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5 |
- |
1 |
= |
4 |
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9 |
- |
5 |
= |
4 |
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18 |
- |
9 |
= |
9 |
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27 |
- |
18 |
= |
9 |
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43 |
- |
27 |
= |
16 |
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59 |
- |
43 |
= |
16 |
|
84 |
- |
59 |
= |
25 |
|
109 |
- |
84 |
= |
25 |
Or:
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1 |
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= |
1 |
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2 |
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4 |
1 |
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= |
5 |
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10 |
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4 |
4 |
1 |
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= |
9 |
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18 |
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9 |
4 |
4 |
1 |
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= |
18 |
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36 |
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9 |
9 |
4 |
4 |
1 |
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= |
27 |
|
54 |
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16 |
9 |
9 |
4 |
4 |
1 |
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= |
43 |
|
86 |
|
16 |
16 |
9 |
9 |
4 |
4 |
1 |
= |
59 |
|
118 |
There is a connection between pyramidal numbers and
odd numbers and the magic numbers of noble gases, as shown in the
table below :
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1 |
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= |
1 |
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2 |
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5 |
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= |
5 |
|
10 |
|
14 |
- |
5 |
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= |
9 |
|
18 |
|
30 |
- |
7 |
- |
5 |
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= |
18 |
|
36 |
|
55 |
- |
9 |
- |
7 |
- |
7 |
- |
5 |
|
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= |
27 |
|
54 |
|
91 |
- |
11 |
- |
9 |
- |
9 |
- |
7 |
- |
7 |
- |
5 |
= |
43 |
|
86 |
Here is the alternative form of this connection, as
shown in the table below:
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1 |
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= |
1 |
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2 |
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4 |
1 |
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= |
5 |
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10 |
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10 |
4 |
- |
3 |
2 |
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= |
9 |
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18 |
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20 |
10 |
- |
4 |
3 |
3 |
2 |
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= |
18 |
|
36 |
|
35 |
20 |
- |
5 |
4 |
4 |
3 |
4 |
3 |
3 |
2 |
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= |
27 |
|
54 |
|
56 |
35 |
- |
6 |
5 |
5 |
4 |
5 |
4 |
4 |
3 |
4 |
3 |
3 |
2 |
= |
43 |
|
86 |
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